PHOTORETICULABLE VARNISH COMPOSITIONS AS BASE COATING AND METHODS OF APPLICATION

专利摘要:
The present invention relates to a kit for the coating of a nail or false nail, and more particularly for the makeup of a nail or false nail, comprising: - a first photocurable cosmetic composition comprising in a physiologically acceptable medium at least one photocrosslinkable compound a) corresponding to the following formula (I): Formula (I) in which: - R1, R2, R3, which may be identical or different, representing a hydrogen atom, a C1-C10 alkyl group, - n representing a integer between 1 and 10, the bond between α and β of carbonyloxy is a single bond, a double bond or is a bond included in a (hetero) ring comprising from 5 to 7 carbon atoms; and a second photocrosslinkable composition comprising, in a physiologically acceptable medium: at least one phtotecreatable compound b) comprising at least one compound (poly) urethane poly (ALK) acrylate comprising a (poly) oxyalkylene unit, at least one phtotecreatable compound, ) comprising at least two carbamate units obtained by reaction with at least one diisocyanate of isophorone diisocyanate type, • at least one (ALK) acrylate monomer, preferably (meth) acrylate, more preferably tetrahydrofurfuryl methacrylate, the present invention also relates to processes particular applications of such a composition.
公开号:FR3013970A1
申请号:FR1362087
申请日:2013-12-04
公开日:2015-06-05
发明作者:Guillaume Kergosien；Carl Riachi；Pape Marina Le
申请人:LOreal SA；
IPC主号:

专利说明:

[0001] The present invention relates to novel photocurable lacquer compositions. BACKGROUND OF THE INVENTION This type of composition preferably corresponds to a base coating applied directly in contact with the nail and / or the false nail. This base coating may also be called first coating in the case of a structure employing a plurality of coatings of distinct compositions. This coating can thus be coated with at least one second coating. In particular, this second coating may be a finishing coating or a colored coating. More particularly, the first coating may be coated with a colored coating as a second coating, itself coated with a finishing coating as a third coating. It also relates to methods for applying such compositions to nails and / or false nails, as well as the use of said compositions for the makeup and / or care of nails and / or false nails. The nail polish compositions can be used as a base for varnish (also called base coat in the English terminology), as a nail makeup product, or as a finishing composition (also called a topcoat according to the English terminology). saxon) to be applied to the nail makeup product, or even as a cosmetic nail care product. These compositions can be applied to both natural nails and false nails. Nail polishes are known from liquid cosmetic compositions, which are used by first depositing a coating on the nail and then subjecting said coating to the action of light radiation, which causes within said coating in situ polymerization and / or crosslinking reactions resulting in most often crosslinked polymer networks. Such photocurable compositions, commonly known as "UV gels" and generally based on crosslinkable compounds of monomeric (meth) acrylate type, make it possible to obtain a good hold of the coating deposited on the nail, and are described, for example, in CA 1 306. 954, US 5,456,905, US 7,375,144 and FR 2,823,105. However, so-called conventional "soak-off" UV gels generally have holding problems when they are not applied by expert manicurists. They also generally require a nail polishing step to sand the nail to promote the holding of the photocured composition in the form of a film, thus significantly damaging the nail. Moreover, the removal of makeup of such compositions is often difficult and may require a step of scraping the nail with a metal tool, an electric sander, or an abrasive file, harmful to the integrity of the nail. Examples of prior art patents to overcome these problems are US2011 / 0081306, US2011 / 0082228, US2011 / 0274633 and US2012 / 0083547. The present invention is distinguished from this state of the art by the development of a composition having superior nail-holding to competing products without sanding by sanding the nail, or with only slight sanding by sanding. the nail, prior to the application of the photocurable composition. In addition, some products may have performance problems concerning, in particular, the quality of makeup. Furthermore, the step of removing make-up of the compositions of the prior art conventionally uses tools intended to scrape the surface of the nail to remove the photocured film of previously applied composition, which may damage the nails. Finally, the present invention aims to provide novel photocurable compositions having, after photocrosslinking of the film, a low content of extractable compounds comprising reactive (meth) acrylate functions. The present invention thus aims to provide novel photocurable compositions which do not exhibit at least one of the disadvantages of the aforementioned compositions. In particular, the present invention aims to provide photocurable compositions which can be removed by conventional organic solvents, such as acetone, without requiring an abrasive tool for the nails. In particular, the present invention aims to provide photocurable compositions which have a good compromise between holding and removing makeup compared to photocurable compositions described in the prior art or existing. The present invention also aims at providing photocurable compositions allowing nail quality makeup, in particular in terms of homogeneity of result and, where appropriate, of color. The present invention aims to provide photocurable compositions that are easy to use, including by the user itself, thus saving time and money.
[0002] The present invention relates to a kit for the coating of a nail or false nail, and more particularly for the makeup of a nail or false nail, comprising: a first photocurable cosmetic composition comprising in a physiologically acceptable medium at least one compound photocrosslinkable a) having the following formula (I): Formula (I) Formula (I) wherein: - R1, R2, R3, identical or different, representing a hydrogen atom, a C1-C10 alkyl group preferably C1, preferably R1 being methyl, preferably R2 and R3 being a hydrogen atom, n being an integer from 1 to 10, preferably 2, the bond between a and 3 carbonyloxy is a single bond, a double bond or is a bond included in a (hetero) ring comprising from 5 to 7 carbon atoms, preferably to 6 carbon atoms, (hetero) ring which may be aromatic or not, prefer aromatic compound, more preferably aryl, such as phenyl; and a second photocrosslinkable composition comprising, in a physiologically acceptable medium: at least one photocrosslinkable compound b) comprising at least one poly (poly) urethane poly (ALK) acrylate compound, preferably polyurethane di (meth) acrylate, more preferably polyurethane dimethacrylate, the (the) photocrosslinkable compound (s) b) comprising a (poly) oxyalkylene unit, in particular comprising a (poly) oxyethylene unit, preferably comprising from 1 to 100 oxyalkylene units, preferably from 5 to 50 oxyalkylene units, and preferably about 8 to 10 oxyalkylene units, preferably identical to that contained in the first composition, at least one photocrosslinkable compound c) comprising at least two carbamate units obtained by reaction with at least one isophorone diisocyanate diisocyanate, at least one monomer ( ALK) acrylate, preferably (meth) acrylate, more preferably tetrahydrofurfuryl The term "photocrosslinkable compounds (a) of formula (I)" is also understood to mean its optical isomers, its geometrical isomers and its base salts. According to preferred embodiments answering at least one of the aforementioned problems: the photo-crosslinkable compound (s) a) have the formula (la): ## STR2 ## la) in which: - R1, R2, R3, which may be identical or different, representing a hydrogen atom, a C1-C10 alkyl, preferably C1-alkyl group, preferably R1 being a methyl, preferably R2 and R3 being a hydrogen atom, - n representing an integer between 1 and 10, preferably 2, the (s) photocrosslinkable compound (s) a) have the formula (Ib): O OH R1V o Formula (Ib) Formula (Ib) in which: R1, R2, R3, which may be identical or different, representing a hydrogen atom, a C1-C10 alkyl, preferably C1-alkyl group, preferably R1 being a methyl, preferably R2 and R3 being a hydrogen atom, - n representing an integer between 1 and 10, preferably equal to 2, the (the) compound (s) (s) photocrosslinkable (s) a) correspond to formula (1c): ## STR2 ## Formula (Ic) Formula (Ic) in which: R1, R2, R3, which may be identical or different, representing a hydrogen atom; C 1 -C 10 alkyl, preferably C 1, preferably R 1 being methyl, preferably R 2 and R 3 being hydrogen, n being an integer from 1 to 10, preferably 2 ; the photocurable compound (s) a) is (are) chosen from compounds of formula (Ia), (Ib) and (Ic), as previously defined, and their mixture; the compound (s) a), corresponding to the formula (I), is (are) present in the first composition at a content greater than or equal to 10% by weight, relative to the weight of the total dry extract of the first composition, in particular ranging from 10 to 25% by weight, preferably from 15 to 20% by weight, relative to the weight of the total solids content of the first composition; the first composition comprises at least one photocurable compound b) comprising at least one poly (poly) urethane poly (ALK) acrylate compound, preferably polyurethane di (meth) acrylate, more preferably polyurethane dimethacrylate, the photocurable compound (s) b) comprising a (poly) oxyalkylene unit, in particular comprising a (poly) oxyethylene unit, preferably comprising from 1 to 100 oxyalkylene units, preferably from 5 to 50 oxyalkylene units, and preferably from approximately 8 to 10 oxyalkylene units, preferably identical to that contained in the first composition; the compound (s) b) corresponds to the following formula (II): ## STR2 ## Formula (II) Formula (II) in which: R 2, R 3, R 4, R 5, and R 6, which may be identical or different, representing a hydrogen atom or a C 1 -C 10 alkyl chain, preferably a hydrogen atom or a methyl group, k and I, which may be identical or different, , between 1 and 10, preferably equal to 2, - m between 1 and 100, preferably between 5 and 50, preferably between 8 and 10, n between 1 and 10, preferably equal to 1, - X and Y, identical or different, representing a C 1 -C 20 alkyl or cycloalkyl group; the compound (s) b) present in the first composition, in particular corresponding to formula (II), is (are) present at a content greater than or equal to 20% by weight per relative to the total weight of the dry extract of the first composition, in particular ranging from 25 to 50% by weight, preferably from 30 to 50% by weight, relative to the weight of the total solids content of the first composition; the compound (s) b) present in the second composition, in particular corresponding to formula (II), is (are) present at a content greater than or equal to 10% by weight, relative to the total weight of the dry extract of the second composition, in particular ranging from 25 to 80% by weight, preferably from 50 to 70% by weight, relative to the weight of the total solids content of the second composition ; - the compound (s) c) responds (respond) to the following formula (IV): Formula (IV) Formula (IV) in which: - R1, R2, R3 and R4, identical or different, representing a a hydrogen atom or a C1-C10 alkyl chain, preferably a hydrogen atom or a methyl group, between 1 and 10, preferably equal to 2, A representing a C1-C10 alkyl group, or a polyurethane comprising from 2 to 20 carbamate units; the compound (s) c), in particular corresponding to the formula (IV), is (are) present in the second composition at a content greater than or equal to 5% of NH O 0 R2 NH weight relative to the total weight of the dry extract of the second composition, in particular ranging from 10 to 80% by weight, preferably from 15 to 70% by weight, relative to the weight of the total solids content of the second composition ; the first composition and the second composition comprise at least one film-forming polymer, preferably chosen from the group consisting of poly (meth) acrylates, polysaccharides and derivatives, and of their mixture, preferably their mixture; the first composition comprises at least one film-forming polymer chosen from the group consisting of poly (meth) acrylates, and preferably a mixture of poly (meth) acrylate (s) and of polysaccharide (s) and derivatives; the second composition comprises at least one film-forming polymer chosen from the group of polysaccharides and derivatives. the film-forming polymer (s) comprises (include) at least one poly (meth) acrylate corresponding to the following formula (III): Formula (III) Formula (III) in which: R1, R2 and R3, which may be identical or different, representing a hydrogen atom or a C1-C10 alkyl group, R1 preferably representing a C4-C10 alkyl group, and R2 and R3 preferably representing a hydrogen atom or a methyl group, - x and y, identical or different, representing an integer between 1 and 100, z representing an integer between 0 and 100, n representing an integer between 1 and 1000; the polysaccharide (s) and polysaccharide derivative (s) is (are) chosen from nitrocellulose and the ethers and esters of polysaccharides, especially of C 2 -C 4, in particular from cellulose acetobutyrates, acetopropionates; cellulose, ethylcelluloses, ethylguars, and mixtures thereof, more preferably selected from nitrocellulose; the film-forming polymer (s) is (are) present in the first composition at a total content greater than or equal to 20%, by weight relative to the total weight of the dry extract of the first composition, in particular ranging from 25 to 40% by weight, relative to the weight of the total solids content of the first composition; the film-forming polymer (s) is (are) present in the second composition at a total content greater than or equal to 0.05% by weight relative to the total weight of the dry extract of the second composition, in particular ranging from 0.1 to 10% by weight, preferably from 0.2 to 5% by weight, relative to the weight of the total solids content of the second composition; the first composition comprises at least one volatile solvent, preferably at least one polar volatile solvent advantageously chosen from the group consisting of C 3 -C 6 esters and ketones and their mixtures; the first composition has a total content of volatile solvent (s) greater than or equal to 30% by weight relative to the total weight of the first composition, in particular ranging from 50 to 70% relative to the total weight of the first composition; the first composition and the second composition comprise at least one photoinitiator, preferably the photoinitiator is chosen from the group consisting of α-hydroxyketones, α-aminoketones, aromatic ketones preferably associated with a hydrogen-donor compound, α-hydroxyketones, α-amino ketones, aromatic diketones and acylphosphine oxides, and mixtures thereof, advantageously in the group consisting of acylphosphine oxides; the first composition comprises at least one acrylate monomer (ALK), preferably distinct from the compounds a), b), c), preferably (meth) acrylate, more preferably tetrahydrofurfuryl methacrylate; the monomer (s) (ALK) acrylate (s) is (are) present in the first composition at a total content greater than or equal to 0.1%, by weight relative to the total weight of the extract; dry from the first composition, in particular ranging from 0.2 to 10% by weight, preferably from 0.5 to 5% by weight, relative to the weight of the total solids content of the first composition; the monomer (s) (ALK) acrylate (s) is (are) present in the second composition at a total content greater than or equal to 2%, by weight relative to the total weight of the dry extract of the second composition, in particular ranging from 5 to 40% by weight, preferably from 10 to 30% by weight, relative to the weight of the total solids content of the second composition; the first composition is transparent; the second composition is transparent or colored. The present invention also relates, according to a second aspect of the invention, to a method of coating the nails and / or false nails, in particular makeup and / or care of the nails and / or false nails, comprising at least the following steps: A) application on a nail or false nail of a first photocrosslinkable composition of the kit as previously defined, by which a coating consisting of at least one layer of said first photocurable composition is deposited; the nail or the coated false nail obtained at the end of step A) to light, UV or visible radiation, C) application to the first coating resulting from step A) and B) from a second composition of the kit as previously defined by which a second coating consisting of at least one layer of said second composition is deposited, D) exposure of the coated nail or nail-nail obtained after step C) to a luminous radiation neux, UV or visible. The present invention relates more particularly to a method of coating the nails and / or false nails, in particular makeup and / or care of the nails and / or false nails, comprising at least the following steps: A) application on a nail or false nail of a first photocurable composition of the kit as previously defined, by which a coating consisting of at least one layer of said first photocurable composition, B) exposure of the nail or false coated nail obtained at the end of step A) at a light, UV or visible radiation, C) application to the first coating resulting from step A) and B) of a second composition of the kit as defined above by which is deposited a second coating consisting of at least one layer of said second composition, D) exposure of the coated nail or false nail obtained at the end of step C) to a light radiation, UV or visible, E) app cation on the second coating resulting from step C) and D) of a third composition, distinct from the first composition and the second composition, by which is deposited a third coating consisting of at least one layer of said third composition , F) exposure of the coated nail or false nail obtained at the end of step E) to light, UV or visible radiation. In such a process, the second coating is preferably a topcoat, optionally free of coloring agent.
[0003] Advantageously, when a third coating of a third composition is applied, the second composition applied as the second coating comprises at least one coloring agent.
[0004] Advantageously, steps C) and D) are repeated a total of twice, the second composition being applied a first time and exposed to light, UV or visible radiation, then being applied a second time and exposed to light, UV or light radiation. visible, preferably steps A) and B), as well as E) and F) are respectively implemented only once.
[0005] In such methods, the second coating is preferably one or preferably a plurality of colored layer (s), comprising at least one coloring agent, and the third coating is preferably a topcoat-free topcoat. coloring.
[0006] The present invention relates to a kit comprising at least a first composition and a second composition. The first composition and the second composition are distinct from each other having at least one difference in the chemical nature of the ingredients used or at least one difference in the content of the ingredients used, preferably both and more preferably having a plurality differences in the chemical nature of the ingredients used and in the content of the ingredients used. A kit within the meaning of the present invention means, for example, that the first and second compositions are sold under the same package, or in two separate packages under one package, or in two separate packages under their respective packaging with a combined use indication. of the first composition and the second composition. A FIRST COMPOSITION A kit according to the present invention comprises at least a first photocurable composition. The contents of the ingredients present in this first composition will be expressly expressed in percentage by weight, relative to the total solids content of this first composition, or in percentage by weight, relative to the total weight of this first composition. Dry extract The first composition according to the invention advantageously comprises a solids content greater than or equal to 30%, in particular 40%, and advantageously less than or equal to 60%, in particular 50%. For the purpose of the present invention, the "dry matter content" denotes the content of non-volatile matter. The amount of dry extract (abbreviated as ES) of a composition according to the invention is measured by means of a commercial halogen desiccant "HALOGEN MOISTURE ANALYZER HR 73" from METTLER TOLEDO. The measurement is based on the weight loss of a sample dried by halogen heating and thus represents the percentage of residual material once the volatiles have evaporated. The measurement protocol is as follows: About 2 g of the composition, hereinafter the sample, are spread on a metal cup. The sample is photocrosslinked under a stream of nitrogen (to prevent the oxygen in the air from inhibiting the crosslinking on the surface of the sample). The metal cup is then introduced into the halogen desiccant mentioned above. The sample is then subjected to a temperature of 105 ° C until a constant weight is obtained. The wet mass of the sample, corresponding to its initial mass before crosslinking, and the dry mass of the sample, corresponding to its mass after crosslinking and halogen heating, are measured by means of a precision balance. The experimental error related to the measurement is of the order of plus or minus 2%. The content of dry extract is calculated as follows: Dry extract content (expressed in% by weight) = 100 × (dry weight / wet mass). Physiologically acceptable medium The cosmetic compositions according to the invention comprise a physiologically acceptable medium.
[0007] By "physiologically acceptable medium" is meant a medium that is particularly suitable for applying a composition of the invention to keratin materials. The physiologically acceptable medium is generally adapted to the nature of the medium to which the composition is to be applied, as well as to the appearance under which the composition is to be packaged. Photocrosslinkable Compounds A composition in accordance with the present invention comprises at least one photocrosslinkable compound a), and advantageously at least one photocrosslinkable compound a) and the photocrosslinkable compound b). In the context of the present invention, the term "photocrosslinkable compounds" denotes organic compounds capable of crosslinking under the action of light radiation, resulting in a crosslinked polymeric network.
[0008] The photo-crosslinkable compounds preferably comprise at least one (meth) acrylate function, namely at least one H 2 C = C (R) -C (O) -O- function, with R = H or CH 3, more preferably R = CH 3. Photocurable compound (s) a) The compositions according to the invention comprise at least one photocrosslinkable compound a). They may comprise a single photo-crosslinkable compound a) or a mixture of several photo-crosslinkable compounds a), preferably a single photocrosslinkable compound a).
[0009] The photocrosslinkable compound (s) a) comprise at least one compound corresponding to the following formula (I): ## STR2 ## Formula (I) Formula (I) in which: R 1, R 2, R 3, identical or different, representing a hydrogen atom, a C 1 -C 10 alkyl group, preferably C 1, preferably R 1 being methyl, preferably R 2 and R 3 being a hydrogen atom, n being an integer inclusive between 1 and 10, preferably equal to 2, the bond between a and [3 of carbonyloxy is a single bond, a double bond or is a bond included in a (hetero) ring comprising from 5 to 7 carbon atoms, from preferably to 6 carbon atoms, (hetero) ring which may be aromatic or not, preferably aromatic, more preferably aryl, such as phenyl. According to one particular embodiment, the photocrosslinkable compound (s) a) correspond to the formula (Ia): ## STR2 ## Formula (Ia) in which: R1, R2, R3, which may be identical or different, representing a hydrogen atom or a C1-C10 alkyl group, preferably C1, preferably R1 being a methyl, preferably R2 and R3 being a hydrogen atom, n being a number; integer of between 1 and 10, preferably 2. According to one preferred embodiment, the photocurable compound (s) a) have the formula (Ib): ## STR2 ## lb) Formula (Ib) in which: - R1, R2, R3, identical or different, representing a hydrogen atom, a C1-C10 alkyl group, preferably C1, preferably R1 being a methyl, preferably R2 and R3 being a hydrogen atom, - n representing an integer between 1 and 10, preferably equal to 2. the photored compound (s) ticulable (s) a) correspond to the formula (1c): ## STR2 ## Formula (Ic) Formula (Ic) in which: R1, R2, R3, identical or different, representing a hydrogen atom, an alkyl group C 1 -C 10, preferably C 1, preferably R 1 being methyl, preferably R 2 and R 3 being a hydrogen atom, - n representing an integer between 1 and 10, preferably equal to 2, in a particularly preferred embodiment, the photocurable compound (s) a) is (are) chosen from compounds of formula (Ia), (Ib) and (Ic) as previously defined, and their mixture. Preferably, the photocrosslinkable compound (s) of formula (I) is (are) chosen from methacryloyloxyethyl maleate, methacryloyloxyethyl succinate, and methacryloyloxyethyl phthalate. Preferably, the compound (s) comprise at least methacryloyloxyethyl maleate, bearing the INCI name HEMA MALEATE, and the name Chemical / IU PAC 2-Butenedioic Acid (2Z) -, Mono [2-Methyl-1-Oxo] Propenyl) Oxy] Ethyl] Ester.
[0010] Compound (s) a), corresponding to formula (I), more preferably methacryloyloxyethyl maleate, are present in the first composition at a content greater than or equal to 10% by weight, relative to the weight of the total solids content of the first composition, in particular ranging from 10 to 25% by weight, preferably from 15 to 20% by weight, relative to the weight of the total solids content of the first composition. Photocurable compound (s) b) A first composition of the kit according to the invention advantageously comprises at least one photocrosslinkable compound b). It may comprise a single photocrosslinkable compound b) or a mixture of several photocrosslinkable compounds b), preferably a single photocurable compound b). The photocrosslinkable compound (s) b) comprise at least one poly (urethane) poly (ALK) acrylate compound comprising a (poly) oxyalkylene unit. In general terms, the term "(poly) urethane poly (ALK) acrylate compound" means any compound comprising at least one urethane functional group -O-O (O) -NH- and having several functions (ALK) acrylate of formula H 2 C = C (R) -C (O) -O-, with R preferably equal to H or ALK, it being understood that ALK represents a C 1 -C 6 alkyl group, preferably C 1 -C 2, more preferably C 1, such as CH 3 preferably, R being equal to CH3.
[0011] The "urethane" function is also called the "carbamate" function. Preferably, the photocurable compound (s) (b) comprise several urethane or carbamate functions. As a poly (urethane) poly (ALK) acrylate compound, poly (ALK) acrylate polyurethane compounds are preferred, especially di (ALK) acrylate polyurethane compounds, in particular di (meth) acrylate polyurethane compounds, more particularly compounds polyurethane dimethacrylates. Thus, the term "poly (meth) acrylate" denotes a compound comprising at least two methacrylate functions, or at least two acrylate functions, or at least one methacrylate function and at least one acrylate function, preferably at least two methacrylate functions. Advantageously, the average number of (meth) acrylate functional groups borne by the photocrosslinkable poly (urethane (meth) acrylate compound (s) intended to form, after crosslinking, a crosslinked polymeric network, is greater than or equal to 2 , for example between 2 and 6, better between 2 and 4, more preferably is equal to 2.
[0012] Preferably, the photocurable compound (s) (b) thus comprises (include) at least one polyurethane dimethacrylate compound comprising a plurality of urethane functional groups -O-C (O) -NH-, in particular at least one two urethane functions, and a plurality of methacrylate functions of formula H 2 C = C (CH 3) -C (O) -O-, in particular at least two methacrylate functions.
[0013] By "(poly) oxyalkylene" is meant a divalent group (poly) alkyleneoxy whose alkylene group is linear or branched and contains from 1 to 6 carbon atoms, the alkylene group being optionally substituted by one or more group (s) hydroxy, preferably being unsubstituted as corresponds to - [CH2] 2 -O- or - compound "(poly) urethane poly (ALK) acrylate comprising a (poly) oxyalkylene" unit, is understood as meaning that photocurable compound (s) b) comprises (include) at least one divalent (poly) oxyalkylene group C1-C6, preferably O2, having from 1 to 100 alkyleneoxy units, in particular from 5 to 50 units alkyleneoxy, and more particularly from about 8 to 10 alkyleneoxy units. Preferably, these (poly) oxyalkylenated groups are polyoxyethylene groups. The photocrosslinkable compound (s) (b) preferably correspond to the following formula (II): ## STR2 ## Formula (II) Formula (II) in which: R 2, R 3, R 4, R 5, and R 6, which may be identical or different, represent a hydrogen atom or a C 1 -C 10 alkyl chain, preferably a hydrogen atom or a methyl group, k and I, which may be identical or between 1 and 10, preferably between 2 and 10, preferably between 5 and 50, preferably between about 8 and 10, n between 1 and 10, preferably equal to 1, - X and Y, identical or different, representing a C 1 -C 20 alkyl or cycloalkyl group.
[0014] This (these) photocrosslinkable compound (s) (b), in particular of formula (II), advantageously has a molecular mass greater than or equal to 1000 g / mol, in particular ranging from 1000 to 5000 g / mol. preferably from 1000 to 3000 g / mol. The compound (s) b) present in the first composition, in particular of formula (II), is present at a content greater than or equal to 20% by weight relative to the total weight of the dry extract of the first composition, in particular ranging from 25 to 50% by weight, preferably from 30 to 50% by weight, relative to the weight of the total solids content of the first composition.
[0015] In the first composition, the photocrosslinkable compound (s) a) of formula (I), and when present (s) the (s) photocrosslinkable compound (s) b), in particular of formula (II), is (are) preferably present (s) at a respective total content such that the weight ratio of the (s) photocurable compound (s) a), in particular of formula (I), and ( photocurable compound (s) b), in particular of formula (II), ranges from 0.1 to 2, in particular from 0.25 to 1. Monomer (s) (ALK) acrylate (s) La first composition of the kit according to the invention comprises at least one monomer (ALK) acrylate, preferably at least one monomer (meth) acrylate, such as a tetrahydrofurfurylmethacrylate compound. ALK represents, when present in the monomer, a C1-C6, preferably C1-C2 alkyl group, more preferably C1 such that CH3, preferably R being 0H3.
[0016] In particular this (these) monomer (s) (ALK) acrylate (s), in particular (meth) acrylate (s), present (s) in the first layer applied to the base layer participate in the improvement of the holding and mechanical properties. (The) monomer (s) (ALK) acrylate (s) is (are) present in the first composition at a total content greater than or equal to 0.1%, by weight relative to the total weight of the dry extract of the first composition, in particular ranging from 0.2 to 10% by weight, preferably from 0.5 to 5% by weight, relative to the weight of the total solids content of the first composition. Film-forming polymer (s) The first composition of the kit according to the invention advantageously also comprises at least one film-forming polymer. It may comprise a single film-forming polymer or a mixture of several film-forming polymers, preferably a mixture of several film-forming polymers.
[0017] The film-forming polymer (s) has (a) function to impart resistance to the photo-crosslinkable composition and to promote the removal of make-up. Preferably, the first compositions according to the invention comprise at least two film-forming polymers. The film-forming polymer (s) is (are) present in the first composition at a total content of greater than or equal to 20% by weight relative to the total weight of the dry extract of the first composition, preferably from 25 to 40% by weight, relative to the weight of the total solids content of the first composition. For the purposes of the present invention, the term "film-forming polymer" denotes a polymer capable of forming on its own (ie, in the absence of an auxiliary film-forming agent or of an external stimulus, for example of the UV type), a isolable film, especially continuous and adherent, on a support, especially on the nails. This film-forming polymer may be chosen from the group consisting of synthetic polymers, of radical type or of polycondensate type, polymers of natural origin, and their mixtures.
[0018] A film-forming polymer that is suitable for the invention may be chosen from at least one poly (meth) acrylate compound, in particular from homopolymers and (meth) acrylate copolymers, preferably from (meth) acrylate copolymers. The poly (meth) acrylate compound (s), in particular the (meth) acrylate copolymer (s) present in the composition, is (are) advantageously capable of being obtained ( s) by: i) polymerizing at least one methyl methacrylate monomer (MMA) and at least one acrylic or methacrylic acid monomer (AA or MAA), or ii) polymerizing at least one monomer of methyl methacrylate (MMA), of at least one monomer having a glass transition temperature of less than 30 ° C such as butyl methacrylate (BMA), butyl acrylate (BA), or 2-ethylhexyl acrylate (2-EHA), and optionally at least one acrylic acid (AA) monomer or methacrylic acid (MAA) monomer. A first composition according to the invention preferably comprises at least one poly (meth) acrylate type film-forming polymer ii) obtained by polymerization of at least one methyl methacrylate monomer (MMA), at least one monomer of glass transition less than 30 ° C such as butyl methacrylate (BMA), butyl acrylate (BA), or 2-ethylhexyl acrylate (2-EHA), and optionally at least one monomer of acrylic acid (AA) or methacrylic acid (MAA). Such a poly (meth) acrylate-type film-forming polymer of type ii) preferably corresponds to the following formula (III): Formula (III) Formula (III) in which: R1, R2 and R3, which may be identical or different, represent an atom of hydrogen or a C 1 -C 10 alkyl group, R 1 preferably being a C 4 -C 10 alkyl group, and R 2 and R 3 preferably being a hydrogen atom or a methyl group, - x and y, the same or different, representing an integer between 1 and 100, z representing an integer between 0 and 100, n representing an integer between 1 and 1000. Preferably, a composition according to the invention comprises at least one film-forming polymer. chosen from at least one polyacrylate compound of formula (III).
[0019] As a variant or preferably additionally, a film-forming polymer that is suitable for the invention may be chosen from polysaccharides and polysaccharide derivatives, such as cellulose or guar gum derivatives. A preferred polysaccharide derivative suitable for the invention may be nitrocellulose or a polysaccharide ester or alkyl ether.
[0020] By "polysaccharide ester or alkyl ether" is meant a polysaccharide formed of repeating units comprising at least two identical or different rings and having a degree of substitution per saccharide unit of between 1.9 and 3, preferably of between 2.2 and 2.9, and more particularly between 2.4 and 2.8. By substitution is meant the functionalization of the hydroxyl groups as ester and / or alkyl ether functions, and / or the functionalization of the carboxylic groups as ester functions. In other words, it may be a polysaccharide partially or totally substituted with ester and / or alkyl ether groups. Preferably, the hydroxyl groups may be substituted by ester and / or alkyl ether C2-04 functions.
[0021] Mention may in particular be made of cellulose esters (such as cellulose acetobutyrates or cellulose acetopropianates), cellulose alkylethers (such as ethylcelluloses), and ethylguars. A film-forming polymer that is suitable for the invention may be chosen from synthetic polymers such as polyurethanes, acrylic polymers, vinyl polymers, polyvinyl butyrals, alkyd resins and ketone / aldehyde resins, resins derived from condensation products of aldehydes, such as arylsulfonamide formaldehyde resins such as toluene sulfonamide formaldehyde resin, epoxy aryl-sulfonamide resins or ethyl tosylamide resins.
[0022] A film-forming polymer that is suitable for the invention may also be chosen from polymers of natural origin, such as plant resins such as dammars, elemi, copals, benzoin; gums such as shellac, sandalwood gum and putty gum. As film-forming polymer, the toluene sulfonamide formaldehyde resins "Ketjentflex MS80" from the company Akzo or "Santolite MHP", "Santolite MS 80" from the company Fontronno or "Resimpol 80" from the company Pan Americana, the alkyd resin, can especially be used. "BECKOSOL ODE 230-70-E" from the company DAINIPPON, the acrylic resin "ACRYLOID B66" of the company ROHM & HAAS, the polyurethane resin "TRIXENE PR 4127" from BAXENDEN, the acetophenone / formaldehyde resin marketed under the reference Synthetic Resin SK by Degussa. According to a particular preferred embodiment, the film-forming polymer is chosen from the group consisting of polysaccharides and polysaccharide derivatives, preferably from nitrocellulose and ethers and esters of polysaccharides, in particular from C2-C4, and more preferentially from acetobutyrates. cellulose, cellulose acetopropionates, ethylcelluloses, ethylguars, and mixtures thereof. According to an advantageous embodiment, the film-forming polymer is chosen from the group consisting of nitrocellulose, cellulose acetopropionate, cellulose acetate butyrate, and (meth) acrylate homopolymers and copolymers, and mixtures thereof. According to an advantageous embodiment, the first compositions of the invention comprise at least one film-forming polymer chosen from nitrocellulose. According to this particular embodiment, the ratio between the weight of the film-forming polymer (s) chosen from the group consisting of polysaccharides and polysaccharide derivatives, in particular the weight of nitrocellulose, on the weight of the photocrosslinkable compounds, in particular the sum of the respective weight of the photocrosslinkable compounds a) and b), is less than or equal to 1, and preferably between 0.3 and 1. According to an advantageous embodiment, the ratio of the total weight of polymer (s) ) film-forming agent (s), in particular chosen from the group consisting of poly (meth) acrylate compounds, in particular of formula (III), and polysaccharides and polysaccharide derivatives, in particular nitrocellulose, on the weight of the compounds photocurable, in particular the sum of the respective weight of the photocrosslinkable compounds a) and b), and optionally of one or more monomer (s) (meth) acrylate (s), such as a tetrahydrofurfurylm compound ethacrylate, is less than or equal to 1, and preferably between 0.3 and 1. Volatile solvent (s) The first composition of the kit according to the invention also advantageously comprises at least one volatile solvent.
[0023] It can therefore comprise a single solvent or a mixture of several volatile solvents, preferably a mixture of several volatile solvents. The first composition has a total content of volatile solvent (s) greater than or equal to 30% by weight relative to the total weight of the composition, in particular ranging from 50 to 70% relative to the total weight of the composition.
[0024] For the purposes of the invention, the term "volatile solvent" is intended to mean a solvent capable of evaporating on contact with keratin materials in less than one hour at ambient temperature and atmospheric pressure. The volatile solvent (s) of the invention are liquid solvents at ambient temperature, having a non-zero vapor pressure at ambient temperature and atmospheric pressure, in particular ranging from 50 Pa to 40,000 Pa (0.375 at 300 mmHg), in particular ranging from 100 Pa to 26664 Pa (0.75 to 200 mmHg), and more particularly ranging from 1000 Pa to 13332 Pa (7.5 to 100 mmHg). Such solvents are intended in particular to thin and reduce the solids content of the composition.
[0025] The solvents are preferably chosen from polar solvents. By "polar" solvent, within the meaning of the present invention, is meant a solvent, or an oil, whose solubility parameter calculated beyond its melting point δ, is different from 0 (J / cm 3)%. The definition and calculation of the solubility parameters in the HANSEN three-dimensional solubility space are described in the article by C. M. Hansen: "The three dimensional solubility parameters" J. Paint Technol. 39, 105 (1967).
[0026] According to this Hansen space: - 6D characterizes the LONDON dispersion forces resulting from the formation of dipoles induced during molecular shocks; - 8p characterizes the DEBYE interaction forces between permanent dipoles as well as the KEESOM interaction forces between induced dipoles and permanent dipoles; - 8h characterizes the specific interaction forces (hydrogen bond, acid / base, donor / acceptor type, etc.); and - 6a is determined by the equation: 8a = (81) 2 6h 2)%.
[0027] The parameters 8p, 8h, 8D and 8a are expressed in (J / cm3)%. In particular, by "polar" solvent is meant a solvent whose chemical structure is formed essentially or even consisting of carbon and hydrogen atoms, and comprising at least one highly electronegative heteroatom such as an oxygen atom. , nitrogen, silicon or phosphorus.
[0028] Preferably, this polar volatile solvent is selected from the group consisting of C3-C6 esters and ketones and mixtures thereof. As polar volatile solvent, mention may especially be made of acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone and alkyl acetates in which the alkyl group comprises from 2 to 5 carbon atoms, such as methyl acetate. ethyl acetate, propyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, and tert-butyl acetate. butyl. Preferably, the polar volatile solvent is selected from the group consisting of ethyl acetate, propyl acetate, such as n-propyl or isopropyl, n-butyl acetate or isobutyl or tert-butyl, isopropanol, and their mixture (s). According to a preferred embodiment, the solvent is a mixture of butyl acetate, ethyl acetate, and propyl acetate. Butyl acetate, ethyl acetate, and isopropanol are preferably present in the first composition at a respective content of 15 to 35% by weight, 15 to 30% by weight, and 5 to 30% by weight, respectively. at 15%, relative to the total weight of the first composition. Photo-initiator (s) The first composition of the kit according to the invention also advantageously comprises at least one photoinitiator.
[0029] It may comprise a single photoinitiator or a mixture of several photoinitiators, preferably a single photoinitiator. The photoinitiators that can be used according to the present invention are known in the art and are described, for example, in "Photoinitiators in the crosslinking of coatings", G. Li Bassi, Double Liaison - Chemistry of Paints, No. 361, November 1985, p. 34-41; "Industrial applications of photoinduced polymerization", Henri Strub, L'Actualité Chimique, February 2000, p.5-13; and "Photopolymers: Theoretical Considerations and Catch Response", Marc, J.M. Abadie, Double Liaison - Paint Chemistry, No. 435-436, 1992, p.28-34.
[0030] These photoinitiators include: α-hydroxyketones, sold for example under the names DAROCUR® 1173 and 4265, IRGACURE® 184, 2959, and 500 by the company BASF, and ADDITOL® CPK by the company CYTEC, the α-aminoketones, sold for example under the names IRGACURE® 907 and 369 by the company BASF, - aromatic ketones marketed for example under the name ESACURE® TZT by LAMBERTI. Mention may also be made of thioxanthones marketed for example under the name ESACURE® ITX by LAMBERTI, and quinones. These aromatic ketones most often require the presence of a hydrogen donor compound such as tertiary amines and especially alkanolamines. It is possible to mention the tertiary amine ESACURE® EDB sold by the company LAMBERTI. the α-dicarbonyl derivatives, the most common representative of which is benzyldimethylketal, marketed under the name IRGACURE® 651 by BASF.
[0031] Other commercial products are marketed by the company LAMBERTI under the name ESACURE® KB1, and the acylphosphine oxides, such as, for example, the bisacylphosphine oxides (BAPO) sold for example under the names IRGACURE® 819, 1700, and 1800, DAROCUR® 4265, LUCIRIN® TPO, and LUCIRIN® TPO-L by BASF. Preferably, the photoinitiator is chosen from the group consisting of α-hydroxyketones, α-aminoketones, aromatic ketones preferably associated with a hydrogen-donor compound, aromatic α-diketones and acylphosphine oxides, and their mixtures.
[0032] An acylphosphine oxide is preferably used in the photocurable composition of the invention.
[0033] As a photoinitiator, mention may be made of LUCIRI NO TPO-L (BASF). The total content of photoinitiator (s) depends on a large number of factors such as, for example, the reactivity of the various components of the mixture, the presence of coloring agent (s), the intensity of the light source or the exposure time. To obtain the desired properties, the (or) photoinitiator (s) is (are) preferably present in the first composition in a total content greater than or equal to 0.1% by weight relative to the total weight of the first photocurable composition, preferably ranging from 0.2 to 5% by weight relative to the total weight of the first photocurable composition. Other constituents The first composition of a kit according to the invention may further contain adjuvants, or additives, chosen in particular from stabilizing agents, coloring agents such as pigments, plasticizers, coalescers, preservatives. , thickening agents, perfumes, cosmetic actives for nail care, spreading agents, anti-foaming agents, and dispersing agents. Of course those skilled in the art will take care to choose these optional additives and additives so that the advantageous properties of the composition according to the invention are not, or not substantially impaired by the addition envisaged. When the composition comprises coloring agents, it is particularly appropriate to adapt the absorption spectrum of the coloring agents used to that of the photoinitiators, or conversely the absorption spectrum of the photoinitiators to that of the coloring agents used, in order to avoid that these two types of compounds absorb light at the same wavelengths. Indeed, the absorption of light by the coloring agents would make the photoinitiators present beyond a certain depth of the coating almost totally ineffective. Preferably, the first composition of the kit according to the invention is transparent.
[0034] As used herein, the term transparent means that the composition has a HAZEBYK index of less than 5 as measured with a KYKHAZEGLOSS type gloss meter. According to one embodiment, the first composition of the kit according to the invention further comprises a coloring agent chosen from the group consisting of soluble dyes, pigments, nacres and flakes.
[0035] The coloring agent (s) may be present in the first composition in a total content greater than or equal to 0.1% by weight relative to the total weight of the layer, ranging from preferably from 0.1 to 5%, advantageously from 0.2 to 1% by weight relative to the total weight of the first composition.
[0036] By "soluble dyes" are meant organic, inorganic or organometallic compounds, soluble in the composition of the invention and intended to color said composition. The dyes are, for example, Sudan Red, DC Red 17, DC Green 6, [3-carotene, soybean oil, Sudan Brown, DC Yellow 11, DC Violet 2, DC Orange 5, and yellow quinoline. By "pigments" it is necessary to include particles of any shape, white or colored, mineral or organic, insoluble in the composition of the invention and intended to color said composition. By "nacres", it is necessary to understand particles of any iridescent form, in particular produced by certain shellfish in their shell or else synthesized. The pigments may be white or colored, mineral and / or organic. Among the inorganic pigments, titanium dioxide, optionally surface-treated, zirconium oxide or cerium oxides, and oxides of zinc, iron (black, yellow or red) or chromium, the violet of manganese, ultramarine blue, chromium hydrate and ferric blue, metal powders such as aluminum powder, copper powder. Among the organic pigments, mention may be made of carbon black, D & C type pigments, and lacquers based on cochineal carmine, barium, strontium, calcium, aluminum.
[0037] Mention may also be made of effect pigments such as particles comprising an organic or inorganic substrate, natural or synthetic, for example glass, acrylic resins, polyester, polyurethane, polyethylene terephthalate, ceramics, aluminas and coated or not with metallic substances. such as aluminum, gold, copper, bronze, or metal oxides such as titanium dioxide, iron oxide, chromium oxide, mineral or organic pigments and mixtures thereof. The pearlescent pigments may be chosen from white pearlescent pigments such as mica coated with titanium, or bismuth oxychloride, colored pearlescent pigments such as titanium mica coated with iron oxides, titanium mica coated with, inter alia, blue. ferric oxide or chromium oxide, titanium mica coated with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride.
[0038] It is also possible to use pigments with goniochromatic properties, in particular liquid crystal or multilayer. It is also possible to use optical brighteners or fibers optionally coated with optical brighteners.
[0039] A first composition of the kit according to the invention may further comprise one or more fillers, especially in a content ranging from 0.01% to 50% by weight, relative to the total weight of the composition, preferably ranging from 0.01 % to 30% by weight. By "fillers" is meant particles of any form, colorless or white, mineral or synthetic, insoluble in the medium of the composition regardless of the temperature at which the composition is manufactured. These fillers serve in particular to modify the rheology or the texture of the composition. The fillers can be mineral or organic of any shape, platelet, spherical or oblong, irrespective of the crystallographic form (for example sheet, cubic, hexagonal, orthorhombic, etc.). Mention may be made of talc, mica, silica, kaolin, polyamide (nylon) powders (Orgasol® from Atochem), poly-β-alanine and polyethylene, tetrafluoroethylene polymer powders (Teflon). ®), lauroyl-lysine, starch, boron nitride, polymeric hollow microspheres such as those of polyvinylidene chloride / acrylonitrile such as Expancel® (Nobel Industrie), copolymers of acrylic acid (Polytrap® from Dow Corning) and silicone resin microbeads (Toshiba Tospearls®, for example), elastomeric polyorganosiloxane particles, precipitated calcium carbonate, magnesium carbonate and hydro-carbonate, hydroxyapatite, hollow silica microspheres (Silica Beads® from Maprecos), glass or ceramic microcapsules, metal soaps derived from organic carboxylic acids containing from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate. SECOND COMPOSITION A kit according to the present invention comprises, in addition to the first photocurable composition, at least a second composition. The contents of the ingredients present in this second composition will be expressly expressed as a percentage by weight, relative to the total solids content of this second composition, or as a percentage by weight, relative to the total weight of this second composition. second composition according to the invention advantageously comprises a solids content greater than or equal to 30%, preferably 40%, more preferably 50%, for example ranging from 40 to 80%, more preferably from 50% to 70%.
[0040] The definition, the material and the measurement protocol are as previously described with reference to the first composition. Physiologically acceptable medium The second composition according to the invention comprises a physiologically acceptable medium. Photocrosslinkable Compounds A second composition according to the present invention comprises at least photocrosslinkable compounds b) and c) and at least one monomer (ALK) acrylate.
[0041] In the context of the present invention, the term "photocrosslinkable compounds" denotes organic compounds capable of crosslinking under the action of light radiation, resulting in a crosslinked polymeric network. The photo-crosslinkable compounds preferably comprise at least one (meth) acrylate function, namely at least one H 2 C = C (R) -C (O) -O- function, with R = H or CH 3, more preferably R = CH 3. Photocurable compound (s) b) A second composition according to the invention comprises at least one photocrosslinkable compound b).
[0042] They may comprise a single photocurable compound b) or a mixture of several photocrosslinkable compounds b), preferably a single photocurable compound b). The photocrosslinkable compound (s) b) comprise at least one poly (urethane) poly (ALK) acrylate compound comprising a (poly) oxyalkylene unit.
[0043] In general, the term "(poly) urethane poly (ALK) acrylate compound" means any compound comprising at least one urethane functional group -O-O (O) NH-, and comprising several functions (ALK) acrylate of formula H 2 C = C (R) -C (O) -O-, with R preferably equal to H or ALK, it being understood that ALK represents a C 1 -C 6 alkyl group, preferably C 1 -C 2 O, more preferably C 1, such as CH 3, preferably R being equal to CH3.
[0044] The "urethane" function is also called the "carbamate" function. Preferably, the photocurable compound (s) (b) comprise several urethane or carbamate functions. As a poly (urethane) poly (ALK) acrylate compound, poly (ALK) acrylate polyurethane compounds are preferred, especially di (ALK) acrylate polyurethane compounds, in particular di (meth) acrylate polyurethane compounds, more particularly compounds polyurethane dimethacrylates. Thus, the term "poly (meth) acrylate" denotes a compound comprising at least two methacrylate functions, or at least two acrylate functions, or at least one methacrylate function and at least one acrylate function, preferably at least two methacrylate functions. Advantageously, the average number of (meth) acrylate functional groups borne by the photocrosslinkable poly (urethane (meth) acrylate compound (s) intended to form, after crosslinking, a crosslinked polymeric network, is greater than or equal to 2 , for example between 2 and 6, better between 2 and 4, more preferably is 2. Preferably, the (the) photocurable compound (s) b) comprises (include) therefore at least one polyurethane compound dimethacrylate comprising a plurality of urethane functional groups -OC (O) -NH-, in particular at least two urethane functional groups, and a plurality of methacrylate functions of formula H 2 C = C (CH 3) -C (O) -O-, in particular with respect to minus two methacrylate functions. By "(poly) oxyalkylene" is meant a divalent group (poly) alkyleneoxy whose alkylene group is linear or branched and contains from 1 to 6 carbon atoms, the alkylene group being optionally substituted by one or more group (s) hydroxy, preferably being unsubstituted as corresponds to - [CH2] 2 -O- or - compound "(poly) urethane poly (ALK) acrylate comprising a (poly) oxyalkylene" unit, is understood as meaning that photocurable compound (s) b) comprises (include) at least one divalent (poly) oxyalkylene group C1-C6, preferably O2, having from 1 to 100 alkyleneoxy units, in particular from 5 to 50 units alkyleneoxy, and more particularly from about 8 to 10 alkyleneoxy units. Preferably, these (poly) oxyalkylenated groups are polyoxyethylene groups. The photocrosslinkable compound (s) (b) preferably have the following formula (II): ## STR2 ## Formula (II) in which: - R1, R2, R3, R4, R5 and R6, identical or different, representing a hydrogen atom or a C1-C10 alkyl chain, preferably a hydrogen atom or a methyl group, - k and I, identical or different between 1 and 10, preferably equal to 2, - m between 1 and 100, preferably between 5 and 50, preferably between 8 and 10, n between 1 and 10, preferably equal to 1, - X and Y, identical or different, representing a C 1 -C 20 alkyl or cycloalkyl group.
[0045] This (these) photocrosslinkable compound (s) (b), in particular of formula (II), advantageously has a molecular mass greater than or equal to 1000 g / mol, in particular ranging from 1000 to 5000 g / mol. preferably from 1000 to 3000 g / mol. The compound (s) b) present in the second composition, in particular corresponding to formula (II), is (are) present at a content greater than or equal to 10% by weight relative to to the total weight of the dry extract of the second composition, in particular ranging from 25 to 80% by weight, preferably from 50 to 70% by weight, relative to the weight of the total solids content of the first composition. Photocurable compound (s) The second composition according to the invention comprises at least one photocrosslinkable compound c) comprising at least two carbamate units obtained by reaction with at least one diisocyanate of isophorone diisocyanate type. The compound (s) c) preferably (corresponds) to the following formula (IV): ## STR2 ## Formula (IV) Formula (IV) in which: R1, R2, R3, and R4, which may be identical or different, representing a hydrogen atom or a C1-C10 alkyl chain, preferably a hydrogen atom or a methyl group, ranging from 1 to 10, preferably equal to 2, -A; representing a C 1 -C 10 alkyl group, or a polyurethane comprising from 2 to 20 carbamate units.
[0046] Compound (s) c), in particular corresponding to formula (IV), is (are) present in the second composition at a content greater than or equal to 5% by weight relative to the total weight of the dry extract of the second composition, in particular ranging from 10 to 80% by weight, preferably from 15 to 70% by weight, relative to the weight of the total solids content of the second composition.
[0047] In the second composition, the photocurable compound (s) b), in particular of formula (II), and the photocrosslinkable compound (s) C), in particular of formula (IV) ), are preferably present at a respective total content such that the weight ratio of the photocurable compound (s) b), in particular of formula (II), and the photocrosslinkable compound (s) (s) ( s) c), in particular of formula (IV), ranges from 0.1 to 10, in particular from 0.25 to 5. Monomer (s) (ALK) acrylate (s) The second composition according to the invention comprises at least at least one monomer (ALK) acrylate, preferably at least one (meth) acrylate monomer, such as a tetrahydrofurfurylmethacrylate compound. ALK represents, when present in the monomer, an alkyl group in 0106, preferably in C1-C2, more preferably in C1 such that CH3, preferably R being equal to CH3. In particular this (these) monomer (s) (ALK) acrylate (s), in particular (meth) acrylate (s), present (s) in the second layer applied to the base layer participate in the improvement of the holding and mechanical properties.
[0048] This (these) monomer (s) (ALK) acrylate (s) is (are) present in the second composition to a total content greater than or equal to 2%, by weight relative to the total weight of the dry extract of the second composition, in particular ranging from 5 to 40% by weight, preferably from 10 to 30% by weight, relative to the weight of the total solids content of the second composition. In the second composition, the photocrosslinkable compound (s) b), in particular of formula (II), the photocrosslinkable compound (s) c), in particular of formula (IV) and the (ALK) acrylate monomer (s) are preferably present at a respective total content such as the weight ratio of the monomer (s) (ALK) acrylate to the sum of the photocrosslinkable compound (s) b), in particular of formula (II), and of the photocurable compound (s) c), in particular of formula (IV), ranges from 0.1 to 2, in particular from 0.2 to 0.5. Film-forming polymer (s) The second composition according to the invention advantageously also comprises at least one film-forming polymer as defined above. It may comprise a single film-forming polymer or a mixture of several film-forming polymers, preferably a single film-forming polymer. The film-forming polymer (s) is (are) present in the second composition at a total content of greater than or equal to 0.05% by weight relative to the total weight of the dry extract of the second composition, in particular ranging from 0.1 to 10% by weight, preferably from 0.2 to 5% by weight, relative to the weight of the total solids content of the second composition. This film-forming polymer may be chosen from the group consisting of synthetic polymers, of radical type or of polycondensate type, polymers of natural origin, and their mixtures. A film-forming polymer that is suitable for the invention may be chosen from at least one poly (meth) acrylate compound, in particular from homopolymers and (meth) acrylate copolymers, preferably from (meth) acrylate copolymers.
[0049] The poly (meth) acrylate compound (s), in particular the (meth) acrylate copolymer (s) present in the composition, is (are) advantageously capable of being obtained ( s) by: iii) polymerization of at least one methyl methacrylate monomer (MMA) and at least one acrylic or methacrylic acid monomer (AA or MAA), or iv) polymerization of at least one monomer of methyl methacrylate (MMA), of at least one monomer having a glass transition temperature of less than 30 ° C such as butyl methacrylate (BMA), butyl acrylate (BA), or 2-ethylhexyl acrylate (2-EHA), and optionally at least one acrylic acid (AA) monomer or methacrylic acid (MAA) monomer. A composition according to the invention preferably comprises at least one poly (meth) acrylate film-forming polymer of type ii) obtained by polymerization of at least one methyl methacrylate monomer (MMA), at least one transition temperature monomer. vitreous material below 30 ° C such as butyl methacrylate (BMA), butyl acrylate (BA), or 2-ethylhexyl acrylate (2-EHA), and optionally at least one acid monomer acrylic (AA) or methacrylic acid (MAA).
[0050] Such a poly (meth) acrylate-type film-forming polymer of type ii) preferably corresponds to the following formula (III): Formula (III) Formula (III) in which: R1, R2 and R3, which may be identical or different, represent an atom of hydrogen or a C1-C10 alkyl group, where R1 is preferably a C4-C10 alkyl group, and R2 and R3 preferably represent a hydrogen atom or a methyl group, - x and y, the same or different, representing an integer between 1 and 100, z representing an integer between 0 and 100, n representing an integer between 1 and 1000.
[0051] Alternatively or additionally, a film-forming polymer suitable for the invention may be chosen from polysaccharides and polysaccharide derivatives, such as cellulose or guar gum derivatives. A preferred polysaccharide derivative suitable for the invention may be nitrocellulose or a polysaccharide ester or alkyl ether.
[0052] By "polysaccharide ester or alkyl ether" is meant a polysaccharide formed of repeating units comprising at least two identical or different rings and having a degree of substitution per saccharide unit of between 1.9 and 3, preferably of between 2.2 and 2.9, and more particularly between 2.4 and 2.8. By substitution is meant the functionalization of the hydroxyl groups as ester and / or alkyl ether functions, and / or the functionalization of the carboxylic groups as ester functions. In other words, it may be a polysaccharide partially or totally substituted with ester and / or alkyl ether groups. Preferably, the hydroxyl groups may be substituted by ester and / or alkyl ether C2-04 functions. Mention may in particular be made of cellulose esters (such as cellulose acetobutyrates or cellulose acetopropianates), cellulose alkylethers (such as ethylcelluloses), and ethylguars. A film-forming polymer that is suitable for the invention may be chosen from synthetic polymers such as polyurethanes, acrylic polymers, vinyl polymers, polyvinyl butyrals, alkyd resins and ketone / aldehyde resins, resins derived from condensation products of aldehydes, such as arylsulfonamide formaldehyde resins such as toluene sulfonamide formaldehyde resin, epoxy aryl-sulfonamide resins or ethyl tosylamide resins.
[0053] A film-forming polymer that is suitable for the invention may also be chosen from polymers of natural origin, such as plant resins such as dammars, elemi, copals, benzoin; gums such as shellac, sandalwood gum and putty gum. As film-forming polymer, the toluene sulfonamide formaldehyde resins "Ketjentflex MS80" from the company Akzo or "Santolite MHP", "Santolite MS 80" from the company Fontronno or "Resimpol 80" from the company Pan Americana, the alkyd resin, can especially be used. "BECKOSOL ODE 230-70-E" from the company DAINIPPON, the acrylic resin "ACRYLOID B66" of the company ROHM & HAAS, the polyurethane resin "TRIXENE PR 4127" from BAXENDEN, the acetophenone / formaldehyde resin marketed under the reference Synthetic Resin SK by Degussa. According to a particular embodiment, the film-forming polymer is chosen from the group consisting of polysaccharides and polysaccharide derivatives, preferably from nitrocellulose and ethers and esters of polysaccharides, in particular from C 2 -C 4, and more preferentially from acetobutyrates of cellulose, cellulose acetopropionates, ethylcelluloses, ethylguars, and mixtures thereof.
[0054] In one embodiment, the film-forming polymer is selected from the group consisting of nitrocellulose, cellulose acetate propionate, cellulose acetate butyrate, and (meth) acrylate homopolymers and copolymers, and mixtures thereof. According to one embodiment, the compositions of the invention comprise at least one film-forming polymer chosen from nitrocellulose. Preferably, a composition according to the invention comprises at least one film-forming polymer chosen from at least one polyacrylate compound of formula (III). According to this particular embodiment, in the second composition, the ratio between the weight of the film-forming polymer (s) and the photo-crosslinkable compounds, in particular the sum of the respective weight of the photocrosslinkable compounds, is less than or equal to 1, and preferably between 0.001 and 0.1. Volatile solvent (s) The second compositions according to the invention may comprise at least one volatile solvent as defined above. According to a particular embodiment, a second composition is free of volatile solvent (s) According to another preferred embodiment, a second composition comprises a total content of solvent (s) less than or equal to 20% by weight, preferably between 0 and 10% by weight, relative to the total weight of the second composition. Photo-initiator (s) A second composition of a kit according to the invention also advantageously comprises at least one photoinitiator.
[0055] They may comprise a single photoinitiator or a mixture of several photoinitiators, preferably a single photoinitiator. The photoinitiators that can be used in the second composition of the kit according to the invention of the present invention are known in the art and are described, for example in "Photoinitiators in the crosslinking of coatings", G. Li Bassi, Double Liaison - Chemistry of Paints, No. 361, November 1985, pp. 34-41; "Industrial applications of photoinduced polymerization", Henri Strub, L'Actualité Chimique, February 2000, p.5-13; and "Photopolymers: Theoretical Considerations and Catch Response", Marc, J.M. Abadie, Double Liaison - Paint Chemistry, No. 435-436, 1992, p.28-34. These photoinitiators include: α-hydroxyketones, sold for example under the names DAROCUR® 1173 and 4265, IRGACURE® 184, 2959, and 500 by the company BASF, and ADDITOL® CPK by the company CYTEC, the α-aminoketones, sold for example under the names IRGACURE® 907 and 369 by the company BASF, - aromatic ketones marketed for example under the name ESACURE® TZT by LAMBERTI. Mention may also be made of thioxanthones marketed for example under the name ESACURE® ITX by LAMBERTI, and quinones. These aromatic ketones most often require the presence of a hydrogen donor compound such as tertiary amines and especially alkanolamines. It is possible to mention the tertiary amine ESACURE® EDB sold by the company LAMBERTI. the α-dicarbonyl derivatives, the most common representative of which is benzyldimethylketal, marketed under the name IRGACURE® 651 by BASF.
[0056] Other commercial products are marketed by the company LAMBERTI under the name ESACURE® KB1, and the acylphosphine oxides, such as, for example, the bisacylphosphine oxides (BAPO) sold for example under the names IRGACURE® 819, 1700, and 1800, DAROCUR® 4265, LUCIRIN® TPO, and LUCIRIN® TPO-L by BASF. Preferably, the photoinitiator is chosen from the group consisting of α-hydroxyketones, α-aminoketones, aromatic ketones preferably associated with a hydrogen-donor compound, aromatic α-diketones and acylphosphine oxides, and their mixtures.
[0057] In the second photocurable composition of the invention, an acylphosphine oxide is preferably used. As a photoinitiator, mention may be made of LUCIRIN® TPO-L (BASF). The total content of photoinitiator (s) depends on a large number of factors such as, for example, the reactivity of the various components of the mixture, the presence of coloring agent (s), the intensity of the light source or the exposure time. To obtain the desired properties, the (or) photoinitiator (s) is (are) preferably present in the second composition in a total content greater than or equal to 0.1% by weight relative to the total weight of the second photocurable composition, preferably ranging from 0.2 to 5% by weight relative to the total weight of the second photocurable composition.
[0058] Other constituents A second composition of a kit according to the invention may further contain adjuvants, or additives, chosen in particular from stabilizing agents, coloring agents such as pigments, plasticizers, coalescers, preservatives , thickening agents, perfumes, cosmetic actives for nail care, spreading agents, anti-foaming agents, and dispersing agents. Of course those skilled in the art will take care to choose these optional additives and additives so that the advantageous properties of the composition according to the invention are not, or not substantially impaired by the addition envisaged. When the composition comprises coloring agents, it is particularly appropriate to adapt the absorption spectrum of the coloring agents used to that of the photoinitiators, or conversely the absorption spectrum of the photoinitiators to that of the coloring agents used, in order to avoid that these two types of compounds absorb light at the same wavelengths. Indeed, the absorption of light by the coloring agents would make the photoinitiators present beyond a certain depth of the coating almost totally ineffective. Preferably, the second composition of the invention is transparent. As used herein, the term transparent means that the composition has a HAZEBYK index of less than 5 as measured with a KYKHAZEGLOSS type gloss meter. According to one embodiment, the second composition of the invention further comprises a coloring agent selected from the group consisting of soluble dyes, pigments, nacres and flakes.
[0059] The coloring agent (s) may be present in the second composition in a total content greater than or equal to 0.1% by weight relative to the total weight of the layer, ranging from preferably from 0.1 to 5%, advantageously from 0.2 to 1% by weight relative to the total weight of the second composition. By "soluble dyes" are meant organic, inorganic or organometallic compounds, soluble in the composition of the invention and intended to color said composition. The dyes are, for example, Sudan Red, DC Red 17, DC Green 6, 3-carotene, soybean oil, Sudan Brown, DC Yellow 11, DC Violet 2, DC Orange 5 , and yellow quinoline.
[0060] By "pigments" it is necessary to include particles of any shape, white or colored, mineral or organic, insoluble in the composition of the invention and intended to color said composition. By "nacres", it is necessary to understand particles of any iridescent form, in particular produced by certain shellfish in their shell or else synthesized. The pigments may be white or colored, mineral and / or organic. Among the inorganic pigments, titanium dioxide, optionally surface-treated, zirconium oxide or cerium oxides, and oxides of zinc, iron (black, yellow or red) or chromium, the violet of manganese, ultramarine blue, chromium hydrate and ferric blue, metal powders such as aluminum powder, copper powder. Among the organic pigments, mention may be made of carbon black, D & C type pigments, and lacquers based on cochineal carmine, barium, strontium, calcium, aluminum.
[0061] Mention may also be made of effect pigments such as particles comprising an organic or inorganic substrate, natural or synthetic, for example glass, acrylic resins, polyester, polyurethane, polyethylene terephthalate, ceramics, aluminas and coated or not with metallic substances. such as aluminum, gold, copper, bronze, or metal oxides such as titanium dioxide, iron oxide, chromium oxide, mineral or organic pigments and mixtures thereof. The pearlescent pigments may be chosen from white pearlescent pigments such as mica coated with titanium, or bismuth oxychloride, colored pearlescent pigments such as titanium mica coated with iron oxides, titanium mica coated with, inter alia, blue. ferric oxide or chromium oxide, titanium mica coated with an organic pigment of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride. It is also possible to use pigments with goniochromatic properties, in particular liquid crystal or multilayer. It is also possible to use optical brighteners or fibers optionally coated with optical brighteners. The second compositions of a kit according to the invention may also comprise one or more fillers, in particular in a content ranging from 0.01% to 50% by weight, relative to the total weight of the composition, preferably ranging from , 01% to 30% by weight.
[0062] By "fillers" is meant particles of any form, colorless or white, mineral or synthetic, insoluble in the medium of the composition regardless of the temperature at which the composition is manufactured. These fillers serve in particular to modify the rheology or the texture of the composition. The fillers can be mineral or organic of any shape, platelet, spherical or oblong, irrespective of the crystallographic form (for example sheet, cubic, hexagonal, orthorhombic, etc.). Mention may be made of talc, mica, silica, kaolin, polyamide (nylon) powders (Orgasol® from Atochem), poly-β-alanine and polyethylene, tetrafluoroethylene polymer powders (Teflon). ®), lauroyl-lysine, starch, boron nitride, polymeric hollow microspheres such as those of polyvinylidene chloride / acrylonitrile such as Expancel® (Nobel Industrie), copolymers of acrylic acid (Polytrap® from Dow Corning) and silicone resin microbeads (Toshiba Tospearls®, for example), elastomeric polyorganosiloxane particles, precipitated calcium carbonate, magnesium carbonate and hydro-carbonate, hydroxyapatite, hollow silica microspheres (Silica Beads® from Maprecos), glass or ceramic microcapsules, metal soaps derived from organic carboxylic acids containing from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate.
[0063] USES OF THE KIT According to one embodiment, the kit according to the invention is intended to be applied to the nails and / or false nails, preferably for the make-up and / or care of the nails and / or false-nails, more preferentially for makeup of the nails and / or false nails.
[0064] In particular, the first and second compositions according to the invention are intended to be used as photocrosslinkable nail polish. Preferably, the first composition is intended to be applied directly to the nails and / or false nails as a layer or base coat. Such a base coating then constitutes a first coating for at least a second photocurable composition according to the invention. The present invention also relates to a process for makeup and / or care of the nails and / or false nails consisting in applying to a nail and / or a false nail a first photocurable composition according to the invention followed by a second photocurable composition according to the invention.
[0065] The radiation suitable for crosslinking the photocurable composition of the present invention has a wavelength of between 210 and 600 nm, preferably between 250 and 420 nm, preferably between 350 and 410 nm. We can also consider the use of lasers. In a preferred embodiment of the invention, use is made of an LED lamp, or a UV lamp and in particular a mercury vapor lamp, possibly doped with other elements, such as gallium, making it possible to modify the spectrum of emission of the light source. The exposure time to radiation of each photocurable coating deposited depends on various factors such as the chemical nature and the content of the reactive components or the desired crosslinking density.
[0066] For nail polish, it will generally seek to obtain satisfactory results for an exposure time of between 10 seconds and 10 minutes, preferably between 30 seconds and 5 minutes. Such a method can implement a UV lamp of power of about 36 W.
[0067] Preferably, the thickness after drying of the first coating is less than or equal to 100 μm, preferably less than or equal to 75 μm. Preferably, the thickness after drying of the second coating is less than or equal to 250 μm, preferably less than or equal to 200 μm. At the end of the last crosslinking step, the coating deposited on the nail or the false nail may have a tacky layer on its surface requiring cleaning of the crosslinked coating using, for example, a solvent such as isopropanol. The present invention also relates to a method for removing makeup from nails and / or false nails, comprising applying a make-up removal composition, such as a conventional solvent described above, to a coated nail or false nail. at least one layer obtained by crosslinking a layer of first composition of the kit according to the invention and at least one layer obtained by crosslinking a layer of second composition of the kit according to the invention, by which is removed said crosslinked layers. The first coating, or base coat, obtained by application of the first composition of the kit according to the invention is coated with a second coating obtained by application of the second composition of the kit according to the invention. In particular, this second coating is chosen from a finishing coating or a colored coating. More particularly, the first coating may be coated with a colored coating as a second coating, and the second coating itself coated with a finishing coating as a third coating. Preferably, each coating consists of a respective photocurable composition and is photocrosslinked according to the conditions described above. According to a particular embodiment, a method of coating the nails and / or false nails, in particular makeup and / or care of the nails and / or false-nails, comprises at least the following steps: A) application on a nail or a false nail of a first composition of a kit according to the invention, by which is deposited a first coating consisting of at least one layer of said photocurable composition, this first coating being applied directly to the contact nail or false nail, and B) exposure of the coated nail or false nail obtained at the end of step A) to a light, UV or visible radiation, C) application on the first coating resulting from step A) and B) of a second composition of a kit according to the invention, preferably separate from the first composition, by which a second coating is deposited consisting of at least one layer of said second composition, D) exposure of the nail or the coated false nail obtained at the end of step C) to a light, UV or visible radiation. In such a process, the second coating is preferably a topcoat, optionally free of coloring agent.
[0068] According to one embodiment, the method of the invention further comprises, before step B), a drying period of the coating deposited at the end of step A), the duration of which may vary from 10 seconds to 10 minutes, typically 30 seconds to 5 minutes. Said drying is generally carried out in air and at room temperature.
[0069] The crosslinked coatings resulting from the crosslinking of step B) and D) have a resistance in time, in terms of resistance to flaking and gloss, significant and especially at the scale of at least one week. It is thus resistant to water, friction and shock, and shows no significant wear or peeling within this time.
[0070] These coatings also have an ability to solubilize or increase in volume and therefore weight when brought into contact with a conventional make-up remover solvent. This ability to solubilize or swell, manifested by the crosslinked coating, is precisely advantageous for its removal when it is applied to the surface of a nail or false nail. Indeed, the coatings can be easily removed by simple makeup removal using a conventional solvent.
[0071] Thus, the first and second compositions of the kit of the invention are advantageously removable from solvents customary in the field of nail polish, and in particular by acetone and ethyl acetate, and mixtures thereof.
[0072] According to a particular embodiment, a method of coating the nails and / or false nails, in particular makeup and / or care of the nails and / or false-nails, comprises at least the following steps: A) application on a nail or a false nail of a first composition of a kit according to the invention, by which is deposited a first coating consisting of at least one layer of said photocurable composition, the first coating being applied directly to the contact nail or false nail, and B) exposure of the coated nail or false nail obtained at the end of step A) to a light, UV or visible radiation, C) application on the first coating resulting from step A) and B) of a second composition of a kit according to the invention, preferably separate from the first composition, by which a second coating is deposited consisting of at least one layer of said second composition, D) exposure of the nail or the coated false-nail obtained at the end of step C) to light, UV or visible radiation, E) application to the second coating resulting from step C) and D) of a third composition, preferably distinct from the first composition and the second composition, by which a third coating is deposited consisting of at least one layer of said third composition, F) exposure of the coated nail or nail-nail obtained after the step E) to light, UV or visible radiation. In such a process, the second coating is preferably a colored layer comprising at least one coloring agent and the third coating is preferably a colorless agent-free topcoat.
[0073] According to a preferred embodiment, when a third coating of a third composition is applied, the second composition applied as the second coating comprises at least one coloring agent. According to a particularly preferred embodiment, the second coating corresponds to one or, preferably, to several colored layers, preferably identical, such as two, comprising at least one coloring agent, and the third coating is preferably a layer of finish, free of coloring agent.
[0074] According to a preferred embodiment, steps C) and D) are repeated a total of twice, the second composition being applied a first time and exposed to light, UV or visible radiation, then being applied a second time and exposed to a light radiation, UV or visible, preferably steps A) and B), as well as E) and F) are respectively implemented only once. The present invention also relates to a kit comprising: - a first photocurable cosmetic composition according to the invention, - a second photocurable cosmetic composition according to the invention, - an abrasive material having a particle size greater than or equal to 200, preferably less than 300, advantageously between 220 and 280, and an LED lamp or a UV lamp.
[0075] The present invention also relates to a method of coating a nail and / or false nail, comprising the following steps: i) the friction of the surface of a nail or false nails with an abrasive material having a greater particle size or equal to 200, preferably less than 300, advantageously between 220 and 280, ii) the application of a first photocurable cosmetic composition according to the invention to the surface of the nail or false nails which has been rubbed following step i), for depositing a layer consisting of at least one layer of said first composition, iii) exposing the coated nail or false nails obtained following step ii) to an LED lamp or a lamp to UV, so that the photocrosslinking is carried out to obtain a crosslinked layer, iv) the application on the nail or false nail coated with the crosslinked layer, obtained after step iii), a second photocrosslinkable composition salt the invention, for depositing a layer consisting of at least one layer of said second composition, and) the exposure of the coated nail or false nails obtained after step iv) to an LED lamp or a UV lamp , so that photocrosslinking is performed to obtain a crosslinked layer. The friction step is carried out for less than 10 seconds, preferably less than 5 seconds, for example for approximately 3 seconds. The weight percentages given in this application can be compared with the percentage by weight of dry matter of the compounds used. unless the contrary is expressly mentioned.
[0076] The invention will be better understood on reading the description which follows, given solely by way of example. EXAMPLE According to a first exemplary embodiment, the following first composition was prepared: Ingredients of the composition of the base coating Content in% Methacryloyloxyethyl maleate 7.5 (HEMA MALEATE - ESSTECH, Inc.) PEG-400 Urethane dimethacrylate (X-726-0000 - ESSTECH, Inc.) 16 TETRAHYDROFURFURYL METHACRYLATE 1.5 (X-958-7446 - ESSTECH, Inc.) METHYL METHYL METHACRYLATE (MMA) / 7 BUTYL METHACRYLATE (BMA) COPOLYMER (PARALOID B 66 100% DOW CHEMICAL) Nitrocellulose 30 % isopropyl alcohol (viscosity: E22 - 1 / 2s) 7.5 (IDYL E35 TX IPA 30% BERGERAC - SNPE) Ethyl acetate 21.15 Propyl acetate 10 Butyl acetate 25 Ethyl-2,4,6-trimethylbenzoylphenylphosphinate photoinitiator 4 (Lucirin TPO-L - BASF) BHT 0.35 (CLARIANT DITERTIOBUTYL 4-HYDROXYTOLUENE - NIPANOX BHT) The ingredients of the composition are introduced into an opaque flask and placed under stirring in the absence of light with a laboratory mixer. the Rayner brand i until a homogeneous mixture is obtained. An aluminum foil will have been placed above the container to avoid evaporation of the solvents.
[0077] On a nail previously frosted for less than 5 seconds using a file size 280, the first composition described above was applied to said nail so as to form a base coat or base layer. After application, the nail is positioned under a 36W UV lamp for 3 minutes to crosslink the composition to form a film. The following finishing composition is then prepared: Ingredients of the finishing composition% TETRAHYDROFURFURYL METHACRYLATE% (X-958-7446 - ESSTECH, Inc.) Isophorone Urethane Dimethacrylate 15 (X-851-1066 - ESSTECH, Inc.) PEG -400 Urethane Dimethacrylate (X-726-0000 - ESSTECH, Inc.) 60 METHYL METHACRYLATE (MMA) / 1 BUTYL METHACRYLATE (BMA) COPOLYMER (PARALOID B 66 100% DOW CHEMICAL) 2,4,6 Ethyl-photoinitiator -trimethylbenzoylphenylphosphinate 4 (Lucirin TPO-L - BASF) The ingredients of the composition are introduced into an opaque bottle and placed under stirring in the absence of light with a Rayneri laboratory mixer until obtaining a homogeneous mixture. An aluminum foil will have been placed above the container to avoid evaporation of the solvents. This composition is applied to the first coating (base coat) as one or more layers to form a finish coat.
[0078] After applying each layer, only one in this case, the nail is positioned under a 36W UV lamp for 3 minutes to crosslink the composition to form a film, this operation being repeated for each layer applied. After cross-linking the last layer, the surface is cleaned with a cotton swab dipped in isopropanol to remove the sticky layer.
[0079] According to another exemplary embodiment, prior to this finishing coating is applied a colored composition similar to this finishing composition, with the difference that this composition comprises one or more coloring agent (s) in addition. Such a colored composition has the following composition: Ingredients of the colored composition% TETRAHYDROFURFURYL METHACRYLATE (X-958-7446 - ESSTECH, Inc.) Isophorone Urethane Dimethacrylate (X-851-1066 - ESSTECH, Inc.) PEG -400 Urethane Dimethacrylate (X-726-0000 - ESSTECH, Inc.) 59 METHYL METHACRYLATE (MMA) / 1 BUTYL METHACRYLATE (BMA) COPOLYMER (PARALOID B 66 100% DOW CHEMICAL) 2,4,6 Ethyl photoinitiator The ingredients of the composition are introduced into an opaque flask and placed under shadowing in the absence of light with a Rayneri laboratory mixer until obtaining a homogeneous mixture. An aluminum foil will have been placed above the container to avoid evaporation of the solvents. After application of the base coat, one or more layers of the colored composition, in this case two, were (are) applied to the base coat. After applying each layer, the nail is positioned under a 36W UV lamp for 3 minutes to crosslink the composition to form a colored film coating. After application of the colored coating and photocrosslinking of this coating in the form of a film, the previously described finishing composition is then applied to this colored coating in the form of one or more layers, in this case a single layer. After applying this layer, the nail is positioned under a 36W UV lamp for 3 minutes to crosslink the composition to form a film finish coat. After cross-linking the last layer, the surface is cleaned with a cotton swab dipped in isopropanol to remove the sticky layer. In the two embodiments of the invention evaluated each comprising a base coating comprising a photocrosslinkable composition according to the invention, there is thus obtained a varnish having a good hold on the nail. To do this, the outfit was appreciated by simple observation at the naked eye after 14 days of its application. This performance of performance is achieved with only a very slight frosting of the nail before application of said compositions, to avoid the conventional invasive method of fixing a photocurable composition on the nails, by sanding the surface of the nail while while maintaining performance that is equivalent to or better than products currently on the market.
[0080] In addition, the ingredients used in the compositions according to the invention make it possible to have, after photocrosslinking of the film, a content of extractable compounds comprising reactive (meth) acrylate functions, with potentially sensitizing effects, extremely low. The varnish can then be removed entirely after having been in contact with acetone for 15 minutes, again without any conventional invasive method using a metal tool, an electric sander, or an abrasive file rubbing against the surface of the nail made up to eliminate the composition. Throughout the application, the wording "comprising a" or "comprising a" means "comprising at least one" or "comprising at least" one unless the contrary is specified.

权利要求:
Claims (7)
[0001]
REVENDICATIONS1. Kit intended for the coating of a nail or false nail, and more particularly intended for the make-up of a nail or false nail, comprising: a first photocurable composition comprising, in a physiologically acceptable medium, at least one photo-crosslinkable compound a) answering with the following formula (1): OH Formula (1) Formula (I) in which: - R1, R2, R3, identical or different, representing a hydrogen atom, a C1-C10 alkyl group, preferably C1 preferably, R 1 being methyl, preferably R 2 and R 5 being a hydrogen atom, n being an integer from 1 to 10, preferably 2, the bond between a and 13 of carbonyloxy is a simple one. bond, a double bond or is a bond included in a (hetero) ring comprising from 5 to 7 carbon atoms, preferably to 6 carbon atoms, (hetero) ring which may be aromatic or non aromatic, preferably aromatic, more preferably a ryl, such as phenyl; and a second photocrosslinkable composition comprising in a physiologically acceptable medium - at least one photocrosslinkable compound b) comprising at least one poly (urethane) poly (ALK) acrylate compound, preferably poly (meth) acrylate polyurethane, more preferably polyurethane dimethacrylate, the photocurable compound (s) b) comprising a (poly) oxyalkylene unit, in particular comprising a (poly) oxyethylene unit, preferably comprising from 1 to 100 oxyalkylene units, preferably from 5 to 50 oxyalkylene units, and preferably about 8 to 10 oxyalkylene units, preferably identical to that contained in the first composition, - at least one photocrosslinkable compound c) comprising at least two carbamate units obtained by reaction with at least one diisocyanate of isophorone diisocyanate type, - at least one monomer (ALK ) acrylate, preferably (meth) acrylate, more preferably tetrahydrofurfuryl methac rylate,
[0002]
2. Kit according to claim 1, wherein the (the) compound (s) a), corresponding to formula (I), is (are) present in the first composition at a content greater than or equal to 10% by weight, relative to the weight of the total dry extract of the first composition, in particular ranging from 10 to 25% by weight, preferably from 15 to 20% by weight, relative to the weight of the total dry extract of the first composition.
[0003]
3. Kit according to claim 1 or 2, wherein the first composition comprises at least one photocrosslinkable compound b) comprising at least one compound (poly) urethane poly (ALK) acrylate, preferably polyurethane di (meth) acrylate, more preferably polyurethane di methacrylate, the photocurable compound (s) b) comprising a (poly) oxyalkylene unit, in particular comprising a (poly) oxyethylene unit, preferably comprising from 1 to 100 oxyalkylene units, preferably from 5 to 50 units oxyalkylene, and preferably about 8 to 10 oxyalkylene units, preferably identical to that contained in the first composition.
[0004]
4. Kit according to claim 1, 2 or 3, wherein the compound (s) b) responds (correspond) to the following formula (II): ## STR2 ## Formula (II) Formula (II) in which: R 3, R 2, R 3, R 4, R 5, and R 5, which may be identical or different, represent a hydrogen atom or a C 1 -C 10 alkyl chain, preferably a hydrogen atom or a methyl group; - k and I, identical or different, between 1 and 10, preferably equal to 2, - m between 1 and 100, preferably between 5 and 50, preferably between about 8 and 10, - n included between 1 and 10, preferably equal to 1, - X and Y, identical or different, representing a C 1 -C 20 alkyl or cycloalkyl group.
[0005]
5. Kit according to any one of the preceding claims, wherein the first composition comprises the compound (s) b), in particular having the formula (II), the compound (s) b) present (s) in the first composition, in particular the formula (II), is (are) present at a content greater than or equal to 20% by weight relative to the total weight of the dry extract of the first composition, in particular ranging from 25 to 50% by weight, preferably from 30 to 50% by weight, relative to the weight of the total solids content of the first composition. 15
[0006]
6. Kit according to any one of the preceding claims, wherein the compound (s) b) present in the second composition, in particular corresponding to formula (II), is (are) present (s). ) at a content greater than or equal to 10% by weight, relative to the total weight of the dry extract of the second composition, in particular ranging from 25 to 80% by weight, preferably from 50 to 70% by weight, relative to relative to the weight of the total solids content of the second composition.
[0007]
7. Kit according to any one of the preceding claims, wherein the compound (s) c) meets (responds) to the following formula (IV): R3 R4 0 0 // A 7 ç NH 0 -0 Embedded image Formula (IV) in which: R1, R2, R3 and R4, which may be identical or different, represent a hydrogen atom or a C1-C10 alkyl chain, preferably a hydrogen atom or a methyl group, ranging from 1 to 10, preferably equal to 2, A representing a C 1 -C 10 alkyl group or a polyurethane comprising from 2 to 20 carbamate units. 8 Kit according to any one of the preceding claims, wherein the compound (s) c), in particular corresponding to the formula (IV), is (are) present in the second composition at a higher content or equal to 5% by weight relative to the total weight of the dry extract of the second composition, in particular ranging from 10 to 80% by weight, preferably from 15 to 70% by weight, relative to the weight of the total dry extract of the second composition. 9. Kit according to any one of the preceding claims, wherein the first composition and the second composition comprise at least one film-forming polymer, preferably selected from the group consisting of poly (meth) acrylates, polysaccharides and derivatives, and their mixture, preferably their mixture. Kit according to any one of the preceding claims, wherein the first composition comprises at least one film-forming polymer selected from the group consisting of poly (meth) acrylates, and preferably a mixture of poly (meth) acrylate (s) and polysaccharide (s) and derivatives. 11. Kit according to any one of the preceding claims, wherein the second composition comprises at least one film-forming polymer chosen from the group of polysaccharides and derivatives. 12. Kit according to any one of claims 9, 10 or 11, wherein the (the) film-forming polymer (s) comprises (include) at least one poly (meth) acrylate corresponding to the following formula (III) Formula (III) 30Formule (III) in which: - R1, R2 and R3, which may be identical or different, represent a hydrogen atom or a C1-C10 alkyl group, R1 preferably representing a C4-C10 alkyl group, and R2 and R3 preferably represent a hydrogen atom or a methyl group, s - x and y, which may be identical or different, representing an integer from 1 to 100, where z represents an integer from 0 to 100, n representing an integer from 1 to 1000. 13. A kit according to any one of claims 9 to 12, wherein the polysaccharide (s) and polysaccharide (s) is (are) selected from nitrocellulose and the ethers and esters of polysaccharides, especially of C2-C4, in particular from acetobutyrates cellulose, cellulose acetopropionates, ethylcelluloses, ethylguars, and mixtures thereof, more preferably selected from nitrocellulose 14. Kit according to any one of claims 9 to 13, wherein the film-forming polymer (s) (s) is (are) present in the first composition at a total content greater than or equal to 20%, by weight relative to the total weight of the dry extract of the first composition, preferably from 25 to 40 % by weight, based on the weight of the total solids content of the first composition. Kit according to any one of claims 9 to 14, wherein the film-forming polymer (s) is (are) present in the second composition at a total content greater than or equal to 0.05. %, by weight relative to the total weight of the dry extract of the second composition, in particular ranging from 0.1 to 10% by weight, preferably from 0.2 to 5% by weight, relative to the weight of the total solids content of the second composition. 16. Kit according to any one of the preceding claims, in which the first composition comprises at least one volatile solvent, preferably at least one polar volatile solvent advantageously chosen from the group consisting of C 3 -C 6 esters and ketones and their mixtures. 17. Kit according to claim 16, wherein the volatile solvent (s) is (are) present in the first composition at a total content greater than or equal to 30% by weight relative to the total weight of the composition, in particular ranging from 50 to 70% relative to the total weight of the first composition. 18. Kit according to any one of the preceding claims, wherein the first composition and the second composition comprise at least one photoinitiator, preferably the photoinitiator is selected from the group consisting of ahydroxyketones, α-aminoketones, aromatic ketones preferably associated with a photoinitiator. hydrogen donor compound, aromatic α-diketones and acylphosphine oxides, and mixtures thereof, preferably in the group consisting of acyl phosphine oxides. 19. Kit according to any one of the preceding claims, wherein the first composition comprises at least one monomer (ALK) acrylate, preferably (meth) acrylate, more preferably tetrahydrofurfuryl methacrylate. 20. Kit according to the preceding claim, wherein the (the) monomer (s) (ALK) acrylate (s) is (are) present (s) in the first composition to a total content greater than or equal to 0.1%, in weight relative to the total weight of the dry extract of the first composition, in particular ranging from 0.2 to 10% by weight, preferably from 0.5 to 5% by weight, relative to the weight of the total dry extract of the first composition. 21. Kit according to any one of the preceding claims, wherein the (the) monomer (s) (ALK) acrylate (s) is (are) present (s) in the second composition to a total content greater than or equal to 2 %, by weight relative to the total weight of the dry extract of the second composition, in particular ranging from 5 to 40% by weight, preferably from 10 to 30% by weight, relative to the weight of the solids content total of the second composition. 22. A method of coating nails and / or false nails, in particular makeup and / or care of nails and / or false nails, comprising at least the following steps: A) application on a nail or false nail of a first photocurable composition of the kit according to any one of claims 1 to 21, whereby a coating consisting of at least one layer of said first photocurable composition is deposited; B) exposure of the coated nail or false nail; at the end of step A) at a light, UV or visible radiation, C) application on the first coating resulting from step A) and B) of a second composition of the kit according to any one of the claims 1 to 21 by which is deposited a second coating consisting of at least one layer of said second composition, D) exposure of the coated nail or false nail obtained at the end of step C) to a light radiation , UV or visible. 23. A method of coating the nails and / or false-nails, especially makeup and / or care of the nails and / or false-nails, comprising at least the following steps: A) application on a fingernail or false a first photocurable composition of the kit according to any one of claims 1 to 21, by which a coating consisting of at least one layer of said first photocurable composition, B) exposure of the nail or coated false-nail obtained at the end of step A) to a light, UV or visible radiation, C) application to the first coating resulting from step A) and B) of a second composition of the kit according to any one of claims 1 to 21 by which a second coating consisting of at least one layer of said second composition is deposited; D) exposing the coated nail or false nail obtained at the end of the step; C) to a light, UV or visible radiation, E) application on the second coating resulting from step C) and D) of a third composition, distinct from the first composition and the second composition, by which a third coating consisting of at least one layer of said third composition is deposited, F) exposure of the coated nail or false nail obtained at the end of step E) to light, UV or visible radiation. 24. A method of coating nails and / or false nails according to claim 23, wherein when a third coating of a third composition is applied, the second composition applied as the second coating comprises at least one coating agent. coloring. 25. The method of coating nails and / or false nails according to claim 23 or 24, wherein steps C) and D) are repeated twice in total, the second composition being applied a first time and exposed to radiation. light, UV or visible, then being applied a second time and exposed to a light radiation, UV or visible, preferably steps A) and B), as well as E) and F) are respectively implemented only one single time.5

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EP3076937B1|2018-09-26|Photo-crosslinkable varnish compositions as base coating and application methods

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EP2928564B1|2018-05-23|Nail makeup method with photocrosslinkable varnish compositions

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FR3013969A1|2015-06-05|PHOTORETICULABLE VARNISH COMPOSITIONS AS BASE COATING AND METHODS OF APPLICATION

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FR3013976A1|2015-06-05|PHOTORETICULABLE VARNISH COMPOSITIONS AS BASE COATING AND METHODS OF APPLICATION

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FR2998796A1|2014-06-06|Making up and/or caring of nails and/or false nails, by applying flexible article comprising layer of film-forming polymer on nail and exposure of the nail to UV or visible light radiation by photocuring a photocurable compound

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FR2998797A1|2014-06-06|PHOTORETICULATE COSMETIC COMPOSITION NOT COLLAPSIBLE

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FR2998794A1|2014-06-06|Kit, useful for making up and/or caring for nails and/or false nails, comprises base composition comprising film-forming polymer, polish composition comprising block copolymer, and finishing composition comprising film-forming polymer

同族专利:

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公开号 | 公开日

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EP3076936B1|2018-08-15|

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WO2015082338A1|2015-06-11|

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CN105813624A|2016-07-27|

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FR3013970B1|2015-11-20|

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JP2017503767A|2017-02-02|

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ES2694832T3|2018-12-27|

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US20160296456A1|2016-10-13|

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EP3076936A1|2016-10-12|

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US20110082228A1|2009-10-05|2011-04-07|Creative Nail Design, Inc.|Removable protective topcoat for artificial nail coatings and methods therefore|

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DE102011102661A1|2011-05-27|2012-11-29|Costrade Beauty Consulting Gmbh|Easily removable nail polish composition|

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US20130263875A1|2012-04-10|2013-10-10|Esschem, Inc.|Curable nail enhancements|

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DE4013250C1|1990-04-26|1991-10-24|Heraeus Kulzer Gmbh, 6450 Hanau, De|

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WO2014157272A1|2013-03-29|2014-10-02|富士フイルム株式会社|Artificial nail composition, artificial nail, method for forming artificial nail, and nail art kit|US10004673B1|2017-02-08|2018-06-26|L'oreal|Hair treatment composition comprising Michael addition product and methods for treating hair|

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JP6916512B2|2017-02-27|2021-08-11|ピアス株式会社|Artificial nail compositions, artificial nails, and artificial nail kits|

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LU100888B1|2018-07-27|2020-01-27|Int Lacquers S A|Improved compositions as a base coating applicable on the nails|

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LU100889B1|2018-07-27|2020-01-27|Int Lacquers S A|Improved compositions as a makeup product applicable to the nails|

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LU100890B1|2018-07-27|2020-01-27|Int Lacquers S A|Improved compositions as a finishing product applicable to the nails|

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GB201819324D0|2018-11-27|2019-01-09|Theunseen|Coating composition|

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JP6656662B1|2019-02-22|2020-03-04|里田化工株式会社|Artificial nail raw material composition, method for curing artificial nail raw material composition, method for producing artificial nail, and artificial nail|

法律状态:
2015-11-10| PLFP| Fee payment|Year of fee payment: 3 |

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2016-11-11| PLFP| Fee payment|Year of fee payment: 4 |

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2017-10-12| PLFP| Fee payment|Year of fee payment: 5 |

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2018-10-11| PLFP| Fee payment|Year of fee payment: 6 |

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2020-10-16| ST| Notification of lapse|Effective date: 20200905 |

优先权:

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申请号 | 申请日 | 专利标题

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FR1362087A|FR3013970B1|2013-12-04|2013-12-04|PHOTORETICULABLE VARNISH COMPOSITIONS AS BASE COATING AND METHODS OF APPLICATION|FR1362087A| FR3013970B1|2013-12-04|2013-12-04|PHOTORETICULABLE VARNISH COMPOSITIONS AS BASE COATING AND METHODS OF APPLICATION|

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CN201480065904.0A| CN105813624A|2013-12-04|2014-11-28|Photo-crosslinkable varnish compositions as base coating and application methods|

---

PCT/EP2014/075923| WO2015082338A1|2013-12-04|2014-11-28|Photo-crosslinkable varnish compositions as base coating and application methods|

---

ES14803158.6T| ES2694832T3|2013-12-04|2014-11-28|Photocrosslinkable enamel compositions as base coatings and application methods|

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JP2016536643A| JP2017503767A|2013-12-04|2014-11-28|Photocrosslinkable varnish composition as base coating and coating method|

---

US15/100,578| US20160296456A1|2013-12-04|2014-11-28|Photo-crosslinkable varnish compositions as base coating and application methods|

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EP14803158.6A| EP3076936B1|2013-12-04|2014-11-28|Photo-crosslinkable varnish compositions as base coating and application methods|